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arxiv: 0704.0372 · v1 · pith:OAXR6FATnew · submitted 2007-04-03 · 🪐 quant-ph

Levy-Lieb constrained-search formulation as a minimization of the correlation functional

classification 🪐 quant-ph
keywords functionalconstrained-searchcorrelationdensityformulationhereminimizationanalyzed
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The constrained-search formulation of Levy and Lieb, which formally defines the exact Hohenberg-Kohn functional for any N-representable electron density, is here shown to be equivalent to the minimization of the correlation functional with respect to the N-1 conditional probability density, where N is number of electrons of the system. The consequences and implications of such a result are here analyzed and discussed via a practical example.

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