The reviewed record of science sign in
Pith

arxiv: 2211.13511 · v4 · pith:QVFIOUYH · submitted 2022-11-24 · cond-mat.stat-mech · cond-mat.soft

Kauzmann Paradox: a crossover due to diminishing local excitations

Reviewed by Pith T0 review T1 audit T2 compute T3 formal T4 kernel pith:QVFIOUYHrecord.jsonopen to challenge →

classification cond-mat.stat-mech cond-mat.soft
keywords entropykauzmannparadoxexcitationslocalmodelssuddentemperature
0
0 comments X
read the original abstract

The configurational entropy of supercooled liquids extrapolates to zero at the Kauzmann temperature, causing a crisis called the Kauzmann paradox. Here, using a class of multicomponent lattice glass models, we study a resolution of the paradox characterized by a sudden but smooth turn in the entropy as temperature goes sufficiently low. A scalar variant of the models reproduces the Kauzmann paradox with thermodynamic properties at very low temperatures dominated by correlations. An exactly solvable vector variant without correlation illustrates that a sudden entropy turn occurs when discrete local excitations are largely suppressed. Despite being disordered and infinitely degenerate, the ground states have zero entropy per particle.

This paper has not been read by Pith yet.

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.