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ExoMol molecular line lists XXXV: a rotation-vibration line list for hot ammonia

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arxiv 1911.10369 v1 pith:SOH5PXJ6 submitted 2019-11-23 astro-ph.SR astro-ph.EP

ExoMol molecular line lists XXXV: a rotation-vibration line list for hot ammonia

classification astro-ph.SR astro-ph.EP
keywords linelistammoniacoyuteexomolsurfacewavenumbersaccurate
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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A new hot line list for $^{14}$NH$_3$ is presented. The line list CoYuTe was constructed using an accurate, empirically refined potential energy surface and a CCSD(T)/aug-cc-pVQZ ab initio dipole moment surface of ammonia, previously reported. The line list is an improvement of the ammonia line list BYTe [Yurchenko et al., Mon. Not. R. Astron. Soc., 413, 1828 (2011)]. The CoYuTe line list covers wavenumbers up to 20000 cm$^{-1}$, i.e. wavelengths beyond 0.5 $\mu$m for temperatures up to 1500 K. Comparisons with the high temperature experimental data from the literature show excellent agrement for wavenumbers below 6000 cm$^{-1}$. The CoYuTe line list contains 16.9 billion transitions and is available from the ExoMol website (www.exomol.com) and the CDS database.

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