Sulphur and zinc abundances in Galactic halo stars revisited

High resolution UVES spectra of 40 main-sequence stars with -3.3 < [Fe/H] < -1.0 are used to derive S, Fe and Zn abundances from lines in the 400 - 950 nm region. For one star we also present novel observations of the SI triplet at 1.046 micron carried out with the ESO VLT CRIRES spectrograph. Comparison of sulphur abundances from the weak and strong SI lines provides important constraints on non-LTE effects. The high sulphur abundances reported by others for some metal-poor stars are not confirmed; instead, when taking non-LTE effects into account, the Galactic halo stars distribute around a plateau at [S/Fe] = +0.2 dex with a scatter of 0.07 dex only. This indicates that sulphur in Galactic halo stars has been made by alpha-capture processes in massive SNe. The observed scatter in S/Fe is, however, much smaller than predicted from current stochastic models of the chemical evolution of the early Galaxy, suggesting that either the models or the calculated yields of massive SNe should be revised. [Zn/Fe] is close to zero for metallicities in the range -2.0 < [Fe/H] < -1.0 but increases to a level of [Zn/Fe] = +0.15 dex in the range -2.7 < [Fe/H] < -2.0. At still lower metallicities [Zn/Fe] rises steeply to a value around [Zn/Fe] = +0.5 dex at [Fe/H] = -3.2. We also examine the behaviour of S/Zn and find that departures from the solar ratio are significantly reduced at all metallicities if non-LTE corrections to the abundances of these two elements are adopted. This effect, if confirmed, would reduce the usefulness of the S/Zn ratio as a diagnostic of past star-formation activity, but would bring closer together the values measured in damped Lyman-alpha systems and in Galactic stars.