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arxiv: cond-mat/0401379 · v1 · submitted 2004-01-21 · ❄️ cond-mat.mtrl-sci · cond-mat.stat-mech

Deriving nonequilibrium interface kinetics from variational principles

classification ❄️ cond-mat.mtrl-sci cond-mat.stat-mech
keywords surfacechemicalgenericherenonequilibriumpotentialprinciplestension
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Nonequilibrium dynamics at interfaces is generally driven by a chemical potential. Here we demonstrate a generic technique to derive the basic equations of motion, boundary conditions and the chemical potential in a consistent way from fundamental variational principles. As a particular example, we consider a solid surface with elastodynamic effects, together with surface energy and tension. We apply the generic results to perform a linear stability analysis of a planar front subjected to uniaxial stress (Asaro-Tiller-Grinfeld instability), here also with surface tension.

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