Viscous Flow and Jump Dynamics in Molecular Supercooled Liquids: II Rotations
classification
❄️ cond-mat.stat-mech
cond-mat.soft
keywords
rotationaldynamicsmolecularsupercooledcorrelationdecoupleddetectdistribution
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The rotational dynamics of a supercooled molecular liquid is investigated by a molecular-dynamics numerical study. We detect rotational jumps with a waiting-time distribution which is well fitted by a truncated power law. At lower temperatures the rotational correlation times are decoupled from the viscosity.
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