shell
shell(n) multiplies the coherence energy constant by the phi-powered block capacity at level n. Chemists using Recognition Science models cite this when scaling atomic radii or electron affinities from the phi-ladder. The definition is a direct algebraic composition with the block_capacity function and requires no lemmas.
claimLet $E_{coh}$ be the coherence energy. The shell scale at level $n$ is $s(n) := E_{coh} · ϕ^{2n}$.
background
The PeriodicBlocks module models the periodic table via phi-packing of orbitals. block_capacity sets the dimensionless capacity of the n-th shell to phi raised to 2n. shell then scales this capacity by the coherence energy drawn from the Constants structure in LawOfExistence, which bundles Knet, Cproj, Ceng, Cdisp and related nonnegativity conditions.
proof idea
The declaration is a direct definition that multiplies Constants.E_coh by the result of block_capacity n. It is a one-line wrapper that applies the block_capacity definition with no tactics or additional lemmas.
why it matters in Recognition Science
This supplies the shell scale used by shellNumber, screeningFactor, and normalizedRadius in AtomicRadii plus eaProxy and distToClosure in ElectronAffinity. It fills the energy-scale slot in the phi-based periodic table proxy, consistent with the T7 eight-tick octave and the phi-ladder mass formula. It closes part of the scaffolding for chemical predictions inside the Recognition framework.
scope and limits
- Does not derive orbital energies from the Schrödinger equation.
- Does not incorporate electron-electron repulsion beyond phi-packing.
- Does not fix a numerical value for E_coh without external input.
- Does not apply to non-integer shell indices.
formal statement (Lean)
17noncomputable def shell (n : Nat) : ℝ := Constants.E_coh * block_capacity n
proof body
Definition body.
18
19/-- Identity: shell scale equals `E_coh` times capacity at each n. -/
used by (30)
-
k_larger_shell_than_li -
na_larger_than_cl -
screeningFactor -
shellNumber -
astatine_in_halogen_list -
eaProxy -
noble_gas_ea_zero -
enProxy -
blocks_holds -
cumulative_closure_eq_noble -
default -
distToNextClosure -
nextClosure -
noble_gas_at_closure -
shellCapacity -
signedValenceCost -
nobleGasBoilingPoint -
bet2_for_galerkin -
CoerciveL2Bound -
RM2Closed -
vev_GeV -
first_shell_capacity -
second_shell_capacity -
shellCapacity -
subshell_capacity_formula -
third_shell_capacity -
dftExchangeCert -
xc_at_phi_band -
xc_closed_shell_zero -
xcContribution