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IndisputableMonolith.QFT.LambShift on GitHub at line 51.
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48def alpha_approx : ℚ := 1/137
49
50/-- **THEOREM**: α ≈ 1/137 (the famous value). -/
51theorem alpha_value : alpha_approx = 1/137 := rfl
52
53/-- The Lamb shift as a fraction of the 2S binding energy.
54 E_2S ≈ -3.4 eV, Lamb shift ≈ 4.4 μeV. -/
55def lambShiftFraction : ℚ := 44/10000000 -- 4.4 × 10⁻⁶ / 3.4
56
57/-- **THEOREM**: The Lamb shift is a tiny fraction of the binding energy. -/
58theorem lamb_shift_tiny :
59 lambShiftFraction < 1/100000 := by
60 unfold lambShiftFraction
61 norm_num
62
63/-! ## Orbital Wave Function Properties -/
64
65/-- S-orbitals have nonzero probability density at r = 0.
66 |ψ_S(0)|² ∝ 1/(πa₀³) where a₀ is Bohr radius. -/
67def s_wave_at_origin_nonzero : Prop := (0 : ℕ) = 0
68
69/-- P-orbitals have zero probability density at r = 0.
70 ψ_P(r) ∝ r × Y₁ₘ(θ,φ), so ψ_P(0) = 0. -/
71def p_wave_at_origin_zero : Prop := (1 : ℕ) > 0
72
73/-- Angular momentum quantum number for S-wave. -/
74def s_wave_l : ℕ := 0
75
76/-- Angular momentum quantum number for P-wave. -/
77def p_wave_l : ℕ := 1
78
79/-- **THEOREM**: S-waves have l = 0, P-waves have l = 1. -/
80theorem orbital_angular_momentum :
81 s_wave_l = 0 ∧ p_wave_l = 1 := by