Cavity thickness changes distort single-wavelength UV/Vis kinetic data in polaritonic chemistry, mitigable by spectral smoothing, and asymptotic extinction must be fitted rather than fixed.
Brawley and Sindhana Pannir-Sivajothi and Ju Eun Yim and Yong Rui Poh and Joel Yuen-Zhou and Matthew Sheldon , title =
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Toward Reliable Spectroscopic Analysis of Reaction Kinetics in Polaritonic Chemistry
Cavity thickness changes distort single-wavelength UV/Vis kinetic data in polaritonic chemistry, mitigable by spectral smoothing, and asymptotic extinction must be fitted rather than fixed.