Including out-of-plane Raman response in TERS theory shows sample-tip scattering contributes only for modes with strong out-of-plane character, while enhancement is highly sensitive to this response and normalized approach curves depend on coherence length.
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Theory for TERS of 2D materials including out-of-plane Raman response
Including out-of-plane Raman response in TERS theory shows sample-tip scattering contributes only for modes with strong out-of-plane character, while enhancement is highly sensitive to this response and normalized approach curves depend on coherence length.