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Pure State Quantum Statistical Mechanics

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abstract

The capabilities of a new approach towards the foundations of Statistical Mechanics are explored. The approach is genuine quantum in the sense that statistical behavior is a consequence of objective quantum uncertainties due to entanglement and uncertainty relations. No additional randomness is added by hand and no assumptions about a priori probabilities are made, instead measure concentration results are used to justify the methods of Statistical Physics. The approach explains the applicability of the microcanonical and canonical ensemble and the tendency to equilibrate in a natural way. This work contains a pedagogical review of the existing literature and some new results. The most important of which are: i) A measure theoretic justification for the microcanonical ensemble. ii) Bounds on the subsystem equilibration time. iii) A proof that a generic weak interaction causes decoherence in the energy eigenbasis. iv) A proof of a quantum H-Theorem. v) New estimates of the average effective dimension for initial product states and states from the mean energy ensemble. vi) A proof that time and ensemble averages of observables are typically close to each other. vii) A bound on the fluctuations of the purity of a system coupled to a bath.

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quant-ph 1

years

2026 1

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UNVERDICTED 1

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Emergence of Thermodynamics from Equilibration in Isolated Quantum Systems

quant-ph · 2026-06-27 · unverdicted · novelty 6.0

Any continuously differentiable function of equilibrating expectation values equilibrates, implying subsystem entropy and conjugate variables equilibrate and total entropy is dynamically maximized under local conservation in bipartite isolated quantum systems.

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  • Emergence of Thermodynamics from Equilibration in Isolated Quantum Systems quant-ph · 2026-06-27 · unverdicted · none · ref 2 · internal anchor

    Any continuously differentiable function of equilibrating expectation values equilibrates, implying subsystem entropy and conjugate variables equilibrate and total entropy is dynamically maximized under local conservation in bipartite isolated quantum systems.