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arxiv: 0806.0224 · v2 · submitted 2008-06-02 · ⚛️ physics.gen-ph · physics.chem-ph

Ionic Kratzer bond theory and vibrational levels for achiral covalent bond HH

classification ⚛️ physics.gen-ph physics.chem-ph
keywords bondcovalentionickratzerlevelsoscillatortheoryvibrational
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A dihydrogen Hamiltonian reduces to the Sommerfeld-Kratzer-potential, adapted for field quantization according to old-quantum theory. Constants omega_e, k_e and r_e needed for the H_2 vibrational system derive solely from hydrogen mass m_H. For H_2, a first principles ionic Kratzer oscillator returns the covalent bond energy within 0,08 % and all levels within 0,02 %, 30 times better than the Dunham oscillator and as accurate as early ab initio QM.

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