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arxiv: 1111.0155 · v2 · pith:NGH4BP7Onew · submitted 2011-11-01 · ❄️ cond-mat.soft · cond-mat.dis-nn· cond-mat.stat-mech

The mode-coupling glass transition in a fluid confined by a periodic potential

classification ❄️ cond-mat.soft cond-mat.dis-nncond-mat.stat-mech
keywords transitionglassperiodiccalculationconfinementfluidmode-couplingpotential
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We show that a fluid under strong spatially periodic confinement displays a glass transition within mode-coupling theory (MCT) at a much lower density than the corresponding bulk system. We use fluctuating hydrodynamics, with confinement imposed through a periodic potential whose wavelength plays an important role in our treatment. To make the calculation tractable we implement a detailed calculation in one dimension. Although we do not expect simple 1d fluids to show a glass transition, our results are indicative of the behaviour expected in higher dimensions. In a certain region of parameter space we observe a three-step relaxation reported recently in computer simulations [S.H. Krishnan, PhD thesis, Indian Institute of Science (2005); Kim et al., Eur. Phys. J-ST 189, 135-139 (2010)] and a glass-glass transition. We compare our results to those of Krakoviack, PRE 75, 031503 (2007) and Lang et al., PRL 105, 125701 (2010).

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