Is Second Law of Thermodynamics Violated for Electron Transition from Lower-Energy Level to Higher-Energy Level

Second law of thermodynamics is applied to a few electronic processes. It is seen that the second law of thermodynamics holds good for all except one mentioned here. The classical approach, based on exact equivalence of emission and absorption spectra, for electron transition from lower energy level (first orbit) to higher energy level (second orbit) violates the second law of thermodynamics. But since second law which implies irreversibility and is universally true, a new explanation of electron transition from lower to higher energy level is proposed which leads to better understanding of several topics such as Fraunhofer lines, Optical laser. Also, interestingly, it is shown that widely different fields such as second law of thermodynamics and special relativity are in fact closely linked to each other. Also, possible links between supersymmetry and new concept of quaternion mass are mentioned.