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arxiv: physics/0608300 · v2 · submitted 2006-08-31 · ⚛️ physics.chem-ph · physics.optics

Modulated conjugation as a means for attaining a record high intrinsic hyperpolarizability

classification ⚛️ physics.chem-ph physics.optics
keywords conjugationhyperpolarizabilityintrinsicmodulatedacceptorapparentattainingbeen
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We report on a series of chromophores that have been synthesized with a modulated conjugation path between donor and acceptor. Hyper-Rayleigh scattering measurements of the best molecule show an enhanced intrinsic hyperpolarizability that breaches the apparent limit of all previously studied molecules.

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