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Disordered ground state in the three-dimensional face-centred frustrated spin-$\frac{5}{2}$ system MnSn(OH)$_\text{6}$
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abstract
Frustrated magnetism in face-centred cubic (fcc) magnetic sublattices remains underexplored but holds considerable potential for exotic magnetic behaviour. Here we report on the crystal structure, magnetic and thermodynamic properties of the $A$-site-vacant double hydroxide perovskite MnSn(OH)$_6$. Despite dominant antiferromagnetic interactions among Mn$^{2+}$ moments, evidenced by a negative Curie-Weiss temperature, the lack of a sharp thermodynamic transition down to 350$\,$mK implies the absence of long-range magnetic order. However, a broad hump in the specific heat at 1.6$\,$K suggests short-range correlations. Neutron diffraction at low temperatures confirms the presence of three-dimensional antiferromagnetic correlations, manifested as diffuse magnetic scattering with a correlation length $\xi = 24.66\,${\AA} and magnetic propagation vectors $\mathbf{k}=(\frac{1}{2}\,\frac{1}{2}\,\frac{1}{2})$ and $(0\,0.625\,0)$ at 20$\,$mK.
Forward citations
Cited by 1 Pith paper
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Stacking disorder in novel ABAC-stacked brochantite, Cu$_4$SO$_4$(OH)$_6$
First synthetic single crystals of brochantite display a tendency toward a new ABAC layer stacking and reveal a possible double magnetic transition near 7 K.
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