Chemical abundances and doppler imaging of the Ap Si/He-wk star HD 100357
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We present the results of time-resolved photometry, abundance analysis and Doppler imaging of an Ap star, HD 100357. The {\it TESS} photometry revealed rotational modulation with a period of 1.6279247 days. Upon inspecting the residuals after removing the rotational period and its harmonics, we found additional frequencies around 15.8054 d$^{-1}$ which we later confirmed with ground-based observations as originating from a nearby star. Using high-resolution spectroscopy, we identified HD 100357 as an Ap Si/He-wk star exhibiting rotational modulation caused by surface abundance spots. The stellar parameters of HD 100357 were determined as $T_{\rm eff}$ = 11,850 K, $\log g$ = 4.57, $\upsilon\sin i$ = 60 km\,s$^{-1}$, and an inclination angle $i$ = 72$^{\circ}$. The detailed abundance analysis revealed strongly overabundant stratified silicon, an overabundance of iron-peak elements and rare earth elements combined with remarkably deficient helium. Mapping of Fe and Cr abundances revealed the existence of ring-shaped regions with a lower concentration of the elements. Their geometry might reflect the orientation of the hypothetical magnetic field of the star, oriented $\sim$90$^{\circ}$ to the rotational axis. HD 100357, with its strong chemical peculiarities and indications of possible magnetic fields, represents an interesting candidate for follow-up spectropolarimetric observations aimed at investigating its magnetic field topology and stellar activity.
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