Noncollinear magnetic structure and magnetoelectric coupling in buckled honeycomb Co₄Nb₂O₉:A single crystal neutron diffraction study

Through analysis of single crystal neutron diffraction data, we present the magnetic structures of magnetoelectric Co4Nb2O9 under various magnetic fields. In zero-field, neutron diffraction experiments below TN=27 K reveal that the Co2+ moments order primarily along the a* direction without any spin canting along the c axis, manifested by the magnetic symmetry C2/c'. The moments of nearest neighbor Co atoms order ferromagnetically with a small cant away from the next nearest neighbor Co moments along the c axis. In the applied magnetic field H//a, three magnetic domains were aligned with their major magnetic moments perpendicular to the magnetic field with no indication of magnetic phase transitions. The influences of magnetic fields on the magnetic structures associated with the observed magnetoelectric coupling are discussed.