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Collisional excitation of HC3N by para- and ortho-H2
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New calculations for rotational excitation of cyanoacetylene by collisions with hydrogen molecules are performed to include the lowest 38 rotational levels of HC3N and kinetic temperatures to 300 K. Calculations are based on the interaction potential of Wernli et al. A&A, 464, 1147 (2007) whose accuracy is checked against spectroscopic measurements of the HC3N-H2 complex. The quantum coupled-channel approach is employed and complemented by quasi-classical trajectory calculations. Rate coefficients for ortho-H2 are provided for the first time. Hyperfine resolved rate coefficients are also deduced. Collisional propensity rules are discussed and comparisons between quantum and classical rate coefficients are presented. This collisional data should prove useful in interpreting HC3N observations in the cold and warm ISM, as well as in protoplanetary disks.
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Inventories of Rich Carbon-Chain Chemistry in Prestellar and Starless Cores in the Perseus Molecular Cloud
A 15-core Yebes 40m survey in Perseus detects a diverse set of carbon-chain molecules, including HC7N in 4 cores, and finds abundance patterns tied to core density and environment.
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