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arxiv 1910.05009 v1 pith:X7GYNH5E submitted 2019-10-11 cond-mat.mtrl-sci

Optical spectroscopy on the photo-response in multiferroic BiFeO₃ at high pressure

classification cond-mat.mtrl-sci
keywords absorptionfeaturesbifeopressurecrystaldependenceexcitationsfield
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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The pressure dependence of light-induced effects in single-crystalline BiFeO$_3$ is studied by optical spectroscopy. At low pressures, we observe three light-induced absorption features with energies just below the two crystal field excitations and the absorption onset, respectively. These absorption features were previously ascribed to excitons, possibly connected with the ultra-fast photostriction effect in BiFeO$_3$. The pressure-induced redshift of the absorption features follows the pressure dependence of the corresponding crystal field excitations and absorption onset, suggesting the link between them. Above the structural phase transition at $P_{\mathrm{c1}}\approx{}3.5$ GPa the three absorption features disappear, suggesting their connection to the polar phase in BiFeO$_3$. The pressure-induced disappearance of the photo-induced features is irreversible upon pressure release.

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