pith:OGLKMY5B
Scaling and Analytical Approximation of Porous Electrode Theory for Reaction-limited Batteries
A lean model governed by four dimensionless numbers simplifies porous electrode theory for reaction-limited batteries.
arxiv:2604.16627 v2 · 2026-04-17 · eess.SY · cs.SY
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Claims
By assuming high-performance electrodes minimize transport limitations and overpotentials, we derive a simplified 'lean model' governed by four dimensionless numbers... For batteries, we derive analytical solutions for standard protocols... our formulae show excellent agreement at negligible computational cost.
The assumption that high-performance electrodes minimize transport limitations and overpotentials, which is invoked to justify collapsing the full porous electrode theory into the lean model (stated in the abstract).
Scaling analysis produces a lean porous electrode model with four Damkohler numbers (Da, Da_p, Da_w, Da_c) and closed-form solutions for battery protocols that match full simulations.
Receipt and verification
| First computed | 2026-07-02T01:18:08.213005Z |
|---|---|
| Builder | pith-number-builder-2026-05-17-v1 |
| Signature | Pith Ed25519
(pith-v1-2026-05) · public key |
| Schema | pith-number/v1.0 |
Canonical hash
7196a663a1f052b28001763f4a1212949cec0740d72a7232e3649fc5a0368401
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curl -sH 'Accept: application/ld+json' https://pith.science/pith/OGLKMY5B6BJLFAABOY7UUEQSSS \
| jq -c '.canonical_record' \
| python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
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Canonical record JSON
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