Finite volume discretization of Laplace and gradient operators is modified to account for internal voltage jumps, enabling 3D current distribution simulations in liquid metal batteries, validated analytically and applied to Li||Bi discharge.
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A P2D electrochemical-thermal-degradation model with consistent parameterization predicts capacity fade trajectories and internal modes for NMC cells across calendar and combined ageing conditions, showing sub-linear to accelerated fade depending on usage.
Metal foam flow field cells outperform serpentine ones under 0.3 V constant voltage cold start, and a variable current mode that raises current density early improves heat generation while limiting water production.
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Linking Calendar and Cycle Ageing in Lithium-Ion Batteries through Consistent Parameterisation of an Electrochemical-Thermal-Degradation Model
A P2D electrochemical-thermal-degradation model with consistent parameterization predicts capacity fade trajectories and internal modes for NMC cells across calendar and combined ageing conditions, showing sub-linear to accelerated fade depending on usage.