The chemical composition of red giants in 47 Tucanae I: Fundamental parameters and chemical abundance patterns

Context: The study of chemical abundance patterns in globular clusters is of key importance to constrain the different candidates for intra-cluster pollution of light elements. Aims: We aim at deriving accurate abundances for a large range of elements in the globular cluster 47 Tucanae (NGC 104) to add new constraints to the pollution scenarios for this particular cluster, expanding the range of previously derived element abundances. Methods: Using tailored 1D LTE atmospheric models together with a combination of equivalent width measurements, LTE, and NLTE synthesis we derive stellar parameters and element abundances from high-resolution, high signal-to-noise spectra of 13 red giant stars near the tip of the RGB. Results: We derive abundances of a total 27 elements (O, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Y, Zr, Mo, Ru, Ba, La, Ce, Pr, Nd, Eu, Dy). Departures from LTE were taken into account for Na, Al and Ba. We find a mean [Fe/H] = $-0.78\pm0.07$ and $[\alpha/{\rm Fe}]=0.34\pm0.03$ in good agreement with previous studies. The remaining elements show good agreement with the literature, but the inclusion of NLTE for Al has a significant impact on the behaviour of this key element. Conclusions: We confirm the presence of an Na-O anti-correlation in 47 Tucanae found by several other works. Our NLTE analysis of Al shifts the [Al/Fe] to lower values, indicating that this may be overestimated in earlier works. No evidence for an intrinsic variation is found in any of the remaining elements.