Chaos and its quantization in dynamical Jahn-Teller systems

We investigate the $E_g \otimes e_g$ Jahn-Teller system for the purpose to reveal the nature of quantum chaos in crystals. This system simulates the interaction between the nuclear vibrational modes and the electronic motion in non-Kramers doublets for multiplets of transition-metal ions. Inclusion of the anharmonic potential due to the trigonal symmetry in crystals makes the system nonintegrable and chaotic. Besides the quantal analysis of the transition from Poisson to Wigner level statistics with increasing the strength of anharmonicity, we study the effect of chaos on the electronic orbital angular momentum and explore the magnetic $g$-factor as a function of the system's energy. The regular oscillation of this factor changes to a rapidly-decaying irregular oscillation by increasing the anharmonicity (chaoticity).