pith. sign in

arxiv: 2607.02117 · v1 · pith:7ZDWTQGYnew · submitted 2026-07-02 · ❄️ cond-mat.str-el · cond-mat.mtrl-sci

Unconventional Mixed-Parity Magnetism in Rare-Earth Tetraborides

Pith reviewed 2026-07-03 05:54 UTC · model grok-4.3

classification ❄️ cond-mat.str-el cond-mat.mtrl-sci
keywords mixed-parity spin splittingaltermagnetismTbB4scalar spin chiralitynon-coplanar magnetismspin textureEdelstein responseBerry curvature dipole
0
0 comments X

The pith

TbB4's non-coplanar magnetic order creates mixed-parity spin textures in momentum space through scalar spin chirality rather than spin-orbit coupling.

A machine-rendered reading of the paper's core claim, the machinery that carries it, and where it could break.

The paper establishes that a compensated three-dimensional magnet can host component-resolved mixed-parity spin splitting, with in-plane components showing odd parity and the out-of-plane component showing even parity. In TbB4 the non-coplanar ground state produces p- and f-wave-like textures in the plane alongside a d-wave altermagnetic texture perpendicular to the plane. This mixing is generated by a staggered Berry phase that originates in the material's scalar spin chirality. A sympathetic reader would care because the resulting structure produces non-relativistic Edelstein and spin Hall responses plus a Berry curvature dipole, identifying a route to spin-charge conversion that does not rely on relativistic effects.

Core claim

The non-coplanar ground state of TbB4 enforces a unique momentum-space spin texture. The in-plane spin components exhibit odd-parity p- and f-wave-like textures, whereas the out-of-plane component retains an even-parity d-wave altermagnetic character. The coexistence of the in-plane odd-parity textures is driven by a staggered Berry phase arising from the inherent scalar spin chirality, not by relativistic spin-orbit coupling. This mixed-parity structure dictates distinct transport fingerprints, including bulk non-relativistic Edelstein and spin Hall responses, as well as a symmetry-allowed Berry curvature dipole.

What carries the argument

The staggered Berry phase generated by scalar spin chirality in the non-coplanar state, which produces the mixed-parity momentum-space spin textures.

If this is right

  • The mixed-parity spin splitting produces a bulk non-relativistic Edelstein response.
  • It also produces spin Hall responses.
  • A symmetry-allowed Berry curvature dipole appears in the material.
  • Rare-earth tetraborides become a platform for engineering complex spin-charge conversion phenomena.

Where Pith is reading between the lines

These are editorial extensions of the paper, not claims the author makes directly.

  • The same chirality-driven mechanism could be tested in other non-coplanar compensated magnets to look for similar mixed-parity textures.
  • Transport experiments on TbB4 that isolate the Edelstein and spin Hall signals would provide a direct check independent of the first-principles band-structure details.
  • Materials with tunable scalar spin chirality might allow external control over the relative strength of odd- and even-parity components.

Load-bearing premise

The first-principles calculations and symmetry analysis correctly identify the non-coplanar ground state and show that scalar spin chirality, rather than spin-orbit coupling, is responsible for the odd-parity in-plane textures.

What would settle it

Measurement of the spin textures or transport responses in TbB4 that match the predictions of dominant spin-orbit coupling instead of scalar spin chirality would falsify the central claim.

Figures

Figures reproduced from arXiv: 2607.02117 by Bongjae Kim, Chang-Jong Kang, Dong-Choon Ryu, Jae-Ho Han.

Figure 1
Figure 1. Figure 1: FIG. 1. (Color Online) Comparative summary of the symmetry-driven phenomena in GdB [PITH_FULL_IMAGE:figures/full_fig_p002_1.png] view at source ↗
Figure 2
Figure 2. Figure 2: FIG. 2. (Color Online) Component-wise spin splitting in the [PITH_FULL_IMAGE:figures/full_fig_p003_2.png] view at source ↗
Figure 3
Figure 3. Figure 3: FIG. 3. (Color Online) (a) Non-relativistic Edelstein response [PITH_FULL_IMAGE:figures/full_fig_p004_3.png] view at source ↗
Figure 4
Figure 4. Figure 4: FIG. 4. (Color Online) Momentum-space distribution of the [PITH_FULL_IMAGE:figures/full_fig_p005_4.png] view at source ↗
read the original abstract

Altermagnetism has advanced the study of compensated magnets by revealing non-relativistic spin splitting, traditionally classified into strictly even- or odd-parity spin textures. Here, we unveil a fundamentally different regime: component-resolved mixed-parity spin splitting in a fully three-dimensional compensated magnet. Using first-principles calculations, tight-binding and $\mathbf{k} \cdot \mathbf{p}$ models, along with spin-group symmetry analysis, we demonstrate that the non-coplanar ground state of $\mathrm{TbB}_4$ enforces a unique momentum-space spin texture. The in-plane spin components exhibit odd-parity $p$- and $f$-wave-like textures, whereas the out-of-plane component retains an even-parity $d$-wave altermagnetic character. Crucially, the coexistence of the in-plane odd-parity textures is driven not by relativistic spin-orbit coupling, but by a staggered Berry phase arising from the inherent scalar spin chirality. This mixed-parity structure dictates distinct transport fingerprints, including bulk non-relativistic Edelstein and spin Hall responses, as well as a symmetry-allowed Berry curvature dipole. These results establish the rare-earth tetraborides as a robust platform for engineering complex spin-charge conversion phenomena.

Editorial analysis

A structured set of objections, weighed in public.

Desk editor's note, referee report, simulated authors' rebuttal, and a circularity audit. Tearing a paper down is the easy half of reading it; the pith above is the substance, this is the friction.

Referee Report

2 major / 2 minor

Summary. The manuscript uses first-principles DFT calculations, tight-binding and k·p models, and spin-group symmetry analysis to argue that the non-coplanar magnetic ground state of TbB4 produces a mixed-parity momentum-space spin texture in this compensated magnet: odd-parity p- and f-wave-like textures for the in-plane spin components and even-parity d-wave altermagnetic character for the out-of-plane component. The key claim is that the in-plane odd-parity components arise from a staggered Berry phase generated by the scalar spin chirality of the non-coplanar order, rather than from relativistic spin-orbit coupling, and that this texture enables distinct bulk transport responses including non-relativistic Edelstein and spin Hall effects plus a Berry curvature dipole.

Significance. If the central attribution to scalar spin chirality holds, the work identifies a new regime of component-resolved mixed-parity spin splitting in altermagnets that is independent of SOC. This would position rare-earth tetraborides as a platform for engineering complex spin-charge conversion phenomena and would extend the classification of compensated magnets beyond strictly even- or odd-parity textures.

major comments (2)
  1. [Abstract and results section on first-principles and model calculations] Abstract and results section on first-principles and model calculations: The load-bearing claim that the odd-parity in-plane textures are driven by staggered Berry phase from scalar spin chirality and not by SOC requires a controlled demonstration. Because the DFT calculations necessarily include SOC for the heavy Tb f-electrons, the manuscript must show either (i) that the same odd-parity textures survive when SOC is switched off while the non-coplanar order is preserved, or (ii) an explicit non-relativistic symmetry analysis of the spin texture. Without this isolation, SOC-induced parity mixing cannot be ruled out.
  2. [k·p model and Berry-phase discussion] k·p model and Berry-phase discussion: The explicit mapping from the scalar spin chirality of the non-coplanar order to the staggered Berry phase that produces the odd-parity components is not shown in sufficient detail to confirm that the parity mixing is SOC-independent. A step-by-step derivation linking the real-space chirality to the momentum-space spin texture in the non-relativistic limit would be required.
minor comments (2)
  1. Figure captions for the spin-texture plots should explicitly state whether the plotted components are obtained with SOC included or excluded.
  2. A short table summarizing the spin-group symmetries and the allowed spin-texture parities under each would improve readability of the symmetry analysis.

Simulated Author's Rebuttal

2 responses · 0 unresolved

We thank the referee for the constructive and insightful comments. We agree that the SOC-independent origin of the odd-parity textures requires a more explicit demonstration and will revise the manuscript to address both points.

read point-by-point responses
  1. Referee: The load-bearing claim that the odd-parity in-plane textures are driven by staggered Berry phase from scalar spin chirality and not by SOC requires a controlled demonstration. Because the DFT calculations necessarily include SOC for the heavy Tb f-electrons, the manuscript must show either (i) that the same odd-parity textures survive when SOC is switched off while the non-coplanar order is preserved, or (ii) an explicit non-relativistic symmetry analysis of the spin texture. Without this isolation, SOC-induced parity mixing cannot be ruled out.

    Authors: We agree that a direct isolation is needed. In the revised manuscript we will add DFT calculations performed with SOC switched off while preserving the non-coplanar magnetic order; these will show that the odd-parity in-plane textures remain. We will also expand the spin-group symmetry analysis to explicitly demonstrate the non-relativistic character of the spin texture. revision: yes

  2. Referee: The explicit mapping from the scalar spin chirality of the non-coplanar order to the staggered Berry phase that produces the odd-parity components is not shown in sufficient detail to confirm that the parity mixing is SOC-independent. A step-by-step derivation linking the real-space chirality to the momentum-space spin texture in the non-relativistic limit would be required.

    Authors: We will add a detailed step-by-step derivation, based on the tight-binding model in the non-relativistic limit, that explicitly connects the real-space scalar spin chirality to the staggered Berry phase and the resulting odd-parity momentum-space spin texture. This derivation will be placed in the main text or supplementary material of the revised version. revision: yes

Circularity Check

0 steps flagged

No circularity; derivation grounded in independent calculations and symmetry analysis

full rationale

The paper derives mixed-parity spin textures from the non-coplanar magnetic order of TbB4 via first-principles DFT, tight-binding/k·p models, and spin-group symmetry analysis. The central attribution to scalar spin chirality (rather than SOC) is presented as a result of these external methods applied to the identified ground state, with no reduction of predictions to fitted inputs, self-definitional loops, or load-bearing self-citations. The derivation chain remains self-contained against external benchmarks and does not exhibit any of the enumerated circular patterns.

Axiom & Free-Parameter Ledger

0 free parameters · 0 axioms · 0 invented entities

Insufficient detail in abstract to identify specific free parameters, axioms, or invented entities; no explicit fitting or new postulated particles mentioned.

pith-pipeline@v0.9.1-grok · 5758 in / 1194 out tokens · 22051 ms · 2026-07-03T05:54:09.182991+00:00 · methodology

discussion (0)

Sign in with ORCID, Apple, or X to comment. Anyone can read and Pith papers without signing in.

Reference graph

Works this paper leans on

75 extracted references · 75 canonical work pages · 4 internal anchors

  1. [1]

    ˇSmejkal, R

    L. ˇSmejkal, R. Gonz´ alez-Hern´ andez, T. Jungwirth, and J. Sinova, Crystal time-reversal symmetry breaking and spontaneous hall effect in collinear antiferromagnets, Sci- ence Advances6, eaaz8809 (2020)

  2. [2]

    ˇSmejkal, J

    L. ˇSmejkal, J. Sinova, and T. Jungwirth, Emerging re- search landscape of altermagnetism, Phys. Rev. X12, 040501 (2022)

  3. [3]

    ˇSmejkal, J

    L. ˇSmejkal, J. Sinova, and T. Jungwirth, Beyond conven- tional ferromagnetism and antiferromagnetism: A phase with nonrelativistic spin and crystal rotation symmetry, Phys. Rev. X12, 031042 (2022)

  4. [4]

    ˇSmejkal, A

    L. ˇSmejkal, A. H. MacDonald, J. Sinova, S. Nakatsuji, and T. Jungwirth, Anomalous hall antiferromagnets, Na- ture Reviews Materials7, 482 (2022)

  5. [5]

    Jungwirth, R

    T. Jungwirth, R. Fernandes, E. Fradkin, A. MacDon- ald, J. Sinova, and L. ˇSmejkal, Altermagnetism: An un- conventional spin-ordered phase of matter, Newton1, 10.1016/j.newton.2025.100162 (2025)

  6. [6]

    Mazin, Editorial: Altermagnetism—a new punch line of fundamental magnetism, Phys

    I. Mazin, Editorial: Altermagnetism—a new punch line of fundamental magnetism, Phys. Rev. X12, 040002 (2022)

  7. [7]

    Z. Zhou, X. Cheng, M. Hu, R. Chu, H. Bai, L. Han, J. Liu, F. Pan, and C. Song, Manipulation of the al- termagnetic order in CrSb via crystal symmetry, Nature 638, 645 (2025)

  8. [8]

    Zhang, H

    Y. Zhang, H. Bai, J. Dai, L. Han, C. Chen, S. Liang, Y. Cao, Y. Zhang, Q. Wang, W. Zhu, F. Pan, and C. Song, Electrical manipulation of spin splitting torque in altermagnetic RuO 2, Nature Communications16, 5646 (2025)

  9. [9]

    Noh, G.-H

    S. Noh, G.-H. Kim, J. Lee, H. Jung, U. Seo, G. So, J. Lee, S. Lee, M. Park, S. Yang, Y. S. Oh, H. Jin, C. Sohn, and J.-W. Yoo, Tunneling magnetoresistance in alter- magnetic RuO 2-based magnetic tunnel junctions, Phys. Rev. Lett.134, 246703 (2025)

  10. [10]

    Liao, Y.-C

    C.-T. Liao, Y.-C. Wang, Y.-C. Tien, S.-Y. Huang, and D. Qu, Separation of inverse altermagnetic spin-splitting effect from inverse spin hall effect in RuO 2, Phys. Rev. Lett.133, 056701 (2024)

  11. [11]

    Z. Feng, X. Zhou, L. ˇSmejkal, L. Wu, Z. Zhu, H. Guo, R. Gonz´ alez-Hern´ andez, X. Wang, H. Yan, P. Qin, X. Zhang, H. Wu, H. Chen, Z. Meng, L. Liu, Z. Xia, J. Sinova, T. Jungwirth, and Z. Liu, An anomalous hall effect in altermagnetic ruthenium dioxide, Nature Elec- tronics5, 735 (2022)

  12. [12]

    Fedchenko, J

    O. Fedchenko, J. Min´ ar, A. Akashdeep, S. W. D’Souza, D. Vasilyev, O. Tkach, L. Odenbreit, Q. Nguyen, D. Kut- nyakhov, N. Wind, L. Wenthaus, M. Scholz, K. Ross- nagel, M. Hoesch, M. Aeschlimann, B. Stadtm¨ uller, M. Kl¨ aui, G. Sch¨ onhense, T. Jungwirth, A. B. Hellenes, G. Jakob, L. ˇSmejkal, J. Sinova, and H.-J. Elmers, Ob- servation of time-reversal s...

  13. [13]

    Gonz´ alez-Hern´ andez, L.ˇSmejkal, K

    R. Gonz´ alez-Hern´ andez, L.ˇSmejkal, K. V´ yborn´ y, Y. Ya- hagi, J. Sinova, T. c. v. Jungwirth, and J. ˇZelezn´ y, Efficient electrical spin splitter based on nonrelativis- tic collinear antiferromagnetism, Phys. Rev. Lett.126, 127701 (2021)

  14. [14]

    Shao, S.-H

    D.-F. Shao, S.-H. Zhang, M. Li, C.-B. Eom, and E. Y. Tsymbal, Spin-neutral currents for spintronics, Nature Communications12, 7061 (2021)

  15. [15]

    ˇSmejkal, A

    L. ˇSmejkal, A. B. Hellenes, R. Gonz´ alez-Hern´ andez, J. Sinova, and T. Jungwirth, Giant and tunneling mag- netoresistance in unconventional collinear antiferromag- nets with nonrelativistic spin-momentum coupling, Phys. Rev. X12, 011028 (2022)

  16. [16]

    S. Lee, S. Lee, S. Jung, J. Jung, D. Kim, Y. Lee, B. Seok, J. Kim, B. G. Park, L. ˇSmejkal, C.-J. Kang, and C. Kim, Broken kramers degeneracy in altermagnetic MnTe, Phys. Rev. Lett.132, 036702 (2024)

  17. [17]

    O. J. Amin, A. Dal Din, E. Golias, Y. Niu, A. Za- kharov, S. C. Fromage, C. J. B. Fields, S. L. Heywood, R. B. Cousins, F. Maccherozzi, J. Krempask´ y, J. H. Dil, D. Kriegner, B. Kiraly, R. P. Campion, A. W. Rushforth, K. W. Edmonds, S. S. Dhesi, L. ˇSmejkal, T. Jungwirth, and P. Wadley, Nanoscale imaging and control of alter- 7 magnetism in MnTe, Nature6...

  18. [18]

    Krempask´ y, L

    J. Krempask´ y, L. ˇSmejkal, S. W. D’Souza, M. Ha- jlaoui, G. Springholz, K. Uhl´ ıˇ rov´ a, F. Alarab, P. C. Constantinou, V. Strocov, D. Usanov, W. R. Pudelko, R. Gonz´ alez-Hern´ andez, A. Birk Hellenes, Z. Jansa, H. Reichlov´ a, Z. ˇSob´ aˇ n, R. D. Gonzalez Betancourt, P. Wadley, J. Sinova, D. Kriegner, J. Min´ ar, J. H. Dil, and T. Jungwirth, Alterm...

  19. [19]

    Osumi, S

    T. Osumi, S. Souma, T. Aoyama, K. Yamauchi, A. Honma, K. Nakayama, T. Takahashi, K. Ohgushi, and T. Sato, Observation of a giant band splitting in alter- magnetic MnTe, Phys. Rev. B109, 115102 (2024)

  20. [20]

    Hariki, A

    A. Hariki, A. Dal Din, O. J. Amin, T. Yamaguchi, A. Badura, D. Kriegner, K. W. Edmonds, R. P. Cam- pion, P. Wadley, D. Backes, L. S. I. Veiga, S. S. Dhesi, G. Springholz, L. ˇSmejkal, K. V´ yborn´ y, T. Jungwirth, and J. Kuneˇ s, X-ray magnetic circular dichroism in alter- magneticα-MnTe, Phys. Rev. Lett.132, 176701 (2024)

  21. [21]

    Takegami, T

    D. Takegami, T. Aoyama, T. Okauchi, T. Yamaguchi, S. Tippireddy, S. Agrestini, M. Garc´ ıa-Fern´ andez, T. Mi- zokawa, K. Ohgushi, K.-J. Zhou, J. Chaloupka, J. Kuneˇ s, A. Hariki, and H. Suzuki, Circular dichroism in reso- nant inelastic x-ray scattering: Probing altermagnetic domains in MnTe, Phys. Rev. Lett.135, 196502 (2025)

  22. [22]

    J. Ding, Z. Jiang, X. Chen, Z. Tao, Z. Liu, T. Li, J. Liu, J. Sun, J. Cheng, J. Liu, Y. Yang, R. Zhang, L. Deng, W. Jing, Y. Huang, Y. Shi, M. Ye, S. Qiao, Y. Wang, Y. Guo, D. Feng, and D. Shen, Large band splitting in g-wave altermagnet CrSb, Phys. Rev. Lett.133, 206401 (2024)

  23. [23]

    Reimers, L

    S. Reimers, L. Odenbreit, L. ˇSmejkal, V. N. Strocov, P. Constantinou, A. B. Hellenes, R. Jaeschke Ubiergo, W. H. Campos, V. K. Bharadwaj, A. Chakraborty, T. Denneulin, W. Shi, R. E. Dunin-Borkowski, S. Das, M. Kl¨ aui, J. Sinova, and M. Jourdan, Direct observation of altermagnetic band splitting in CrSb thin films, Nature Communications15, 2116 (2024)

  24. [24]

    G. Yang, Z. Li, S. Yang, J. Li, H. Zheng, W. Zhu, Z. Pan, Y. Xu, S. Cao, W. Zhao, A. Jana, J. Zhang, M. Ye, Y. Song, L.-H. Hu, L. Yang, J. Fujii, I. Vobornik, M. Shi, H. Yuan, Y. Zhang, Y. Xu, and Y. Liu, Three- dimensional mapping of the altermagnetic spin splitting in CrSb, Nature Communications16, 1442 (2025)

  25. [25]

    Biniskos, M

    N. Biniskos, M. dos Santos Dias, S. Agrestini, D. Svit´ ak, K.-J. Zhou, J. Posp´ ıˇ sil, and P.ˇCerm´ ak, Systematic map- ping of altermagnetic magnons by resonant inelastic x- ray circular dichroism, Nature Communications16, 9311 (2025)

  26. [26]

    C. Li, M. Hu, Z. Li, Y. Wang, W. Chen, B. Thiagara- jan, M. Leandersson, C. Polley, T. Kim, H. Liu, C. Fulga, M. G. Vergniory, O. Janson, O. Tjernberg, and J. van den Brink, Topological weyl altermagnetism in CrSb, Com- munications Physics8, 311 (2025)

  27. [27]

    Y.-P. Zhu, X. Chen, X.-R. Liu, Y. Liu, P. Liu, H. Zha, G. Qu, C. Hong, J. Li, Z. Jiang, X.-M. Ma, Y.-J. Hao, M.-Y. Zhu, W. Liu, M. Zeng, S. Jayaram, M. Lenger, J. Ding, S. Mo, K. Tanaka, M. Arita, Z. Liu, M. Ye, D. Shen, J. Wrachtrup, Y. Huang, R.-H. He, S. Qiao, Q. Liu, and C. Liu, Observation of plaid-like spin split- ting in a noncoplanar antiferromagn...

  28. [28]

    A. B. Hellenes, T. Jungwirth, R. Jaeschke-Ubiergo, A. Chakraborty, J. Sinova, and L. ˇSmejkal,p-wave mag- nets (2024), arXiv:2309.01607 [cond-mat.mes-hall]

  29. [29]

    Brekke, P

    B. Brekke, P. Sukhachov, H. G. Giil, A. Brataas, and J. Linder, Minimal models and transport properties of unconventionalp-wave magnets, Phys. Rev. Lett.133, 236703 (2024)

  30. [30]

    Q. Song, S. Stavri´ c, P. Barone, A. Droghetti, D. S. An- tonenko, J. W. F. Venderbos, C. A. Occhialini, B. Ilyas, E. Erge¸ cen, N. Gedik, S.-W. Cheong, R. M. Fernandes, S. Picozzi, and R. Comin, Electrical switching of ap-wave magnet, Nature642, 64 (2025)

  31. [31]

    Odd-Parity Altermagnetism Originated from Orbital Orders

    Z.-Y. Zhuang, D. Zhu, D. Liu, Z. Wu, and Z. Yan, Odd-parity altermagnetism originated from orbital or- ders (2025), arXiv:2508.18361 [cond-mat.mes-hall]

  32. [32]

    Yamada, M

    R. Yamada, M. T. Birch, P. R. Baral, S. Okumura, R. Nakano, S. Gao, M. Ezawa, T. Nomoto, J. Masell, Y. Ishihara, K. K. Kolincio, I. Belopolski, H. Sagayama, H. Nakao, K. Ohishi, T. Ohhara, R. Kiyanagi, T. Naka- jima, Y. Tokura, T.-h. Arima, Y. Motome, M. M. Hirschmann, and M. Hirschberger, A metallicp-wave magnet with commensurate spin helix, Nature646, 8...

  33. [33]

    McNally,p-wave magnetism in a metal, Nature Mate- rials25, 16 (2026)

    D. McNally,p-wave magnetism in a metal, Nature Mate- rials25, 16 (2026)

  34. [34]

    Q. N. Meier, A. Carta, C. Ederer, and A. Cano, Net and compensated altermagnetism from staggered orbital order: Layer-dependent spin splitting in sr n+1crno3n+1, Phys. Rev. Lett.136, 116705 (2026)

  35. [35]

    Y. Yu, M. B. Lyngby, T. Shishidou, M. Roig, A. Kreisel, M. Weinert, B. M. Andersen, and D. F. Agterberg, Odd- parity magnetism driven by antiferromagnetic exchange, Phys. Rev. Lett.135, 046701 (2025)

  36. [36]

    P. Liu, J. Li, J. Han, X. Wan, and Q. Liu, Spin-group symmetry in magnetic materials with negligible spin- orbit coupling, Phys. Rev. X12, 021016 (2022)

  37. [37]

    Z. Xiao, J. Zhao, Y. Li, R. Shindou, and Z.-D. Song, Spin space groups: Full classification and applications, Phys. Rev. X14, 031037 (2024)

  38. [38]

    X. Chen, J. Ren, Y. Zhu, Y. Yu, A. Zhang, P. Liu, J. Li, Y. Liu, C. Li, and Q. Liu, Enumeration and representa- tion theory of spin space groups, Phys. Rev. X14, 031038 (2024)

  39. [39]

    Jiang, Z

    Y. Jiang, Z. Song, T. Zhu, Z. Fang, H. Weng, Z.-X. Liu, J. Yang, and C. Fang, Enumeration of spin-space groups: Toward a complete description of symmetries of magnetic orders, Phys. Rev. X14, 031039 (2024)

  40. [40]

    N. A. A. Pari, R. Jaeschke-Ubiergo, A. Chakraborty, L. ˇSmejkal, and J. Sinova, Nonrelativistic linear edel- stein effect in helical EuIn2As2, Phys. Rev. B112, 024404 (2025)

  41. [41]

    Gonz´ alez-Hern´ andez, P

    R. Gonz´ alez-Hern´ andez, P. Ritzinger, K. V´ yborn´ y, J. ˇZelezn´ y, and A. Manchon, Non-relativistic torque and edelstein effect in non-collinear magnets, Nature Com- munications15, 7663 (2024)

  42. [42]

    M. Hu, O. Janson, C. Felser, P. McClarty, J. van den Brink, and M. G. Vergniory, Spin hall and edelstein ef- fects in chiral non-collinear altermagnets, Nature Com- munications16, 8529 (2025)

  43. [43]

    Chakraborty, A

    A. Chakraborty, A. Birk Hellenes, R. Jaeschke-Ubiergo, T. Jungwirth, L. ˇSmejkal, and J. Sinova, Highly efficient non-relativistic edelstein effect in nodalp-wave magnets, Nature Communications16, 7270 (2025)

  44. [44]

    R. R. Neumann, R. Jaeschke-Ubiergo, R. Zarzuela, L. ˇSmejkal, J. Sinova, and A. Mook, Odd-parity-wave magonons and nonrelativistic thermal edelstein effect 8 (2026), arXiv:2603.05415

  45. [45]

    J. Lai, T. Yu, P. Liu, L. Liu, G. Xing, X.-Q. Chen, and Y. Sun,d-wave flat fermi surface in altermagnets enables maximum charge-to-spin conversion, Phys. Rev. Lett.135, 256702 (2025)

  46. [46]

    J. A. Blanco, P. J. Brown, A. Stunault, K. Katsumata, F. Iga, and S. Michimura, Magnetic structure of Gdb 4 from spherical neutron polarimetry, Phys. Rev. B73, 212411 (2006)

  47. [47]

    L. Ye, T. Suzuki, and J. G. Checkelsky, Electronic trans- port on the shastry-sutherland lattice in ising-type rare- earth tetraborides, Phys. Rev. B95, 174405 (2017)

  48. [48]

    R. D. Johnson and S. W. Lovesey, Magnetic symmetries of terbium tetraboride (Tbb4) revealed by resonant x-ray bragg diffraction, Phys. Rev. B110, 104405 (2024)

  49. [49]

    H. Sim, S. Lee, K.-P. Hong, J. Jeong, J. R. Zhang, T. Kamiyama, D. T. Adroja, C. A. Murray, S. P. Thomp- son, F. Iga, S. Ji, D. Khomskii, and J.-G. Park, Spon- taneous structural distortion of the metallic shastry- sutherland system Dyb 4 by quadrupole-spin-lattice cou- pling, Phys. Rev. B94, 195128 (2016)

  50. [50]

    Etourneau, J

    J. Etourneau, J. Mercurio, A. Berrada, P. Hagenmuller, R. Georges, R. Bourezg, and J. Gianduzzo, The magnetic and electrical properties of some rare earth tetraborides, Journal of the Less Common Metals67, 531 (1979)

  51. [51]

    K. H. J. Buschow and J. H. N. Creyghton, Magnetic prop- erties of rare earth tetraborides, The Journal of Chemical Physics57, 3910 (1972)

  52. [52]

    H. C. Choi, A. Laref, J. H. Shim, S. K. Kwon, and B. I. Min, Electronic structures and magnetic properties of rb4 (r=yb,pr,gd,tb,dy), Journal of Applied Physics105, 07E107 (2009)

  53. [53]

    G. A. Wigger, E. Felder, R. Monnier, H. R. Ott, L. Pham, and Z. Fisk, Low-temperature phase transitions in the induced-moment system Prb 4, Phys. Rev. B72, 014419 (2005)

  54. [54]

    Misawa, K

    R. Misawa, K. Arakawa, T. Yoshioka, H. Ueda, F. Iga, K. Tamasaku, Y. Tanaka, and T. Kimura, Resonant x-ray diffraction study using circularly polarized x rays on an- tiferromagnetic tbb4, Phys. Rev. B108, 134433 (2023)

  55. [55]

    Kresse and J

    G. Kresse and J. Furthm¨ uller, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set, Phys. Rev. B54, 11169 (1996)

  56. [57]

    Kresse and D

    G. Kresse and D. Joubert, From ultrasoft pseudopoten- tials to the projector augmented-wave method, Phys. Rev. B59, 1758 (1999)

  57. [58]

    The Supplemental Material includes Refs

    See Supplemental Material for further computational de- tails, the electronic structures ofRB 4, spin textures on the Fermi surfaces, tight-binding andk·pmodels, the ef- fect of spin-orbit coupling on the spin textures and Edel- stein response, as well as the Berry curvature and Berry curvature dipole in the absence of spin-orbit coupling. The Supplementa...

  58. [59]

    H. Li, H. Gao, L. P. Zˆ arbo, K. V´ yborn´ y, X. Wang, I. Garate, F. Doˇ gan, A. ˇCejchan, J. Sinova, T. Jung- wirth, and A. Manchon, Intraband and interband spin- orbit torques in noncentrosymmetric ferromagnets, Phys. Rev. B91, 134402 (2015)

  59. [60]

    Hence, the symmetry operation{I sC −1 4z ||C4z}be- comes{I sC −1 4z ||KC4z} ≡T{C −1 4z ||C4z}, whereTis the time-reversal operation

    The spin-only inversionI s is forced to become anti- unitary (incorporating the complex conjugation operator K) in order to preserve the spin commutation relations when evaluated as a quantum operator in the Kubo for- mula. Hence, the symmetry operation{I sC −1 4z ||C4z}be- comes{I sC −1 4z ||KC4z} ≡T{C −1 4z ||C4z}, whereTis the time-reversal operation

  60. [61]

    Sodemann and L

    I. Sodemann and L. Fu, Quantum nonlinear hall effect induced by berry curvature dipole in time-reversal in- variant materials, Phys. Rev. Lett.115, 216806 (2015)

  61. [62]

    Mixed-Parity Altermagnetism in Collinear Spin-Orbital Magnets

    Z.-Y. Zhuang, J.-X. Hu, S.-B. Zhang, L.-H. Hu, and Z. Yan, Mixed-parity altermagnetism in collinear spin- orbital magnets (2026), arXiv:2605.05205

  62. [63]

    Tunable Odd-Parity Spin Splittings in Altermagnets

    Y. Yu, Tunable odd-parity spin splittings in altermagnets (2026), arXiv:2605.03026

  63. [64]

    Unconventional Mixed-Parity Magnetism in Rare-Earth Tetraborides

    G. Y. Guo, S. Murakami, T.-W. Chen, and N. Nagaosa, Intrinsic spin hall effect in platinum: First-principles cal- culations, Phys. Rev. Lett.100, 096401 (2008). END MA TTER Appendix A: Spin-Space Group Symmetry Elements in TbB4— Based on the spin-space group (SSG) analysis, the non-coplanar magnetic ground state of TbB 4 com- prises 16 symmetry operations...

  64. [65]

    Standard Kinetic Hamiltonian Hkin(k) The 8×8 standard kinetic Hamiltonian is given by: Hkin(k) =hkin(k)⊗σ0 where hkin(k) is the 4×4 spin-independent kinetic matrix and σ0 is the 2×2 identity matrix. To accurately capture the energy band dispersion and the topological crossing features near the Fermi level—particularly around the M-point— hkin(k) incorpora...

  65. [66]

    For itinerant electrons, this chiral spin texture acts as an emergent fictitious gauge field (Berry phase)

    Complex Kinetic Hamiltonian HB(k) Even in the absence of spin-orbit coupling (SOC), the non-coplanar magnetic ordering of the Tb ions yields a non-zero scalar spin chirality, Si·(Sj×Sk)̸= 0. For itinerant electrons, this chiral spin texture acts as an emergent fictitious gauge field (Berry phase). Due to the specific non-coplanar magnetic structure of TbB...

  66. [67]

    Exchange Interaction Hex The conduction electrons interact with the localized, non-coplanar magnetic moments of the Tb ions via the s−f exchange coupling. The interaction Hamiltonian at site i is−Jsf si·Si, where si is the conduction electron spin operator (represented by Pauli matrices) and Si is the normalized local spin moment of the Tb ion. The exchan...

  67. [68]

    7 and SFIG

    Model Parameters The tight-binding parameters used to reproduce the key features of the DFT calculations (e.g., the crossing at the M-point and the spin texture on the Fermi surface) are: ˆ E0 =−0.4 eV (On-site energy) ˆ t =−0.5 eV (Nearest-neighbor hopping) ˆ t′=−0.3 eV (Dimer hopping) ˆ t3 = 0.05 eV (Next-nearest-neighbor hopping) ˆ Jsf =−0.15 eV (s−f e...

  68. [69]

    We expand the elements of the total kinetic Hamiltonian in Eq

    T A YLOR EXP ANSION OF THE KINETIC MA TRIX A T THE M-POINT We define the momentum near the M-point as k = M + q = (π/a+qx,π/a+qy), where|q|≪1. We expand the elements of the total kinetic Hamiltonian in Eq. (1) up to the cubic order,O(q3), to capture the dominant symmetries. 1.1 Nearest-Neighbor Hopping ( t) and Staggered Berry Phase ( λ) Substituting kx =...

  69. [70]

    L ¨OWDIN DOWNFOLDING AND THE EFFECTIVE SPIN HAMIL TONIAN To extract the effective physics at the Fermi level, we project the 8×8 HamiltonianH(M + q) onto the low-energy degenerate subspace utilizing L¨ owdin partitioning. The resulting 2×2 effective Hamiltonian for the conduction electrons in the pseudo-spin subspace takes the generic form: Heff (q) =ε0(q...

  70. [71]

    However, the staggered Berry phase ( λ̸= 0) breaks this cancellation

    COEXISTENCE OF p-W A VE,d-W A VE, ANDf -W A VE SPIN SYMMETRIES 3.1 The Inner Pocket (In-Plane): p-wave Symmetry During downfolding, the pure real-hopping linear terms (±itqxa and±itqya) destructively interfere and cancel out due to the staggered s−f exchange potential. However, the staggered Berry phase ( λ̸= 0) breaks this cancellation. The symmetric rea...

  71. [72]

    Heiba, W

    Z. Heiba, W. Sch¨ afer, E. Jansen, and G. Will, Low-temperature structural phase transitions of tbb4 and erb4 studied by high resolution x-ray diffraction and profile analysis, Journal of Physics and Chemistry of Solids 47, 651 (1986)

  72. [73]

    Kresse and D

    G. Kresse and D. Joubert, From ultrasoft pseudopotentials to the projector augmented-wave method, Phys. Rev. B 59, 1758 (1999)

  73. [74]

    Kresse and J

    G. Kresse and J. Furthm¨ uller, Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set, Phys. Rev. B 54, 11169 (1996)

  74. [75]

    J. P. Perdew, K. Burke, and M. Ernzerhof, Generalized gradient approximation made simple, Phys. Rev. Lett. 77, 3865 (1996)

  75. [76]

    R. D. Johnson and S. W. Lovesey, Magnetic symmetries of terbium tetraboride (Tbb 4) revealed by resonant x-ray bragg diffraction, Phys. Rev. B 110, 104405 (2024)